You would undoubtedly be a more efficient user with these shortcuts - difficulty is remembering them all! So here is a short compilation...
More Windows 7 resources:
Firstly, where Win is written in this text, please use the Windows Key:
Windows 7 Keyboard Shortcuts:
Win +Home: Clear all but the active window.
Win+Space: All windows become transparent so you can see through to the desktop.
Win+Up arrow: Maximize the active window.
Shift+Win+Up arrow: Maximize the active window vertically.
Win+Down arrow: Minimize the window/Restore the window if it's maximized.
Win+Left/Right arrows: Dock the window to each side of the monitor.
Shift+Win+Left/Right arrows: Move the window to the monitor on the left or right.
You can also interact with windows by dragging them with the mouse:
Drag window to the top: Maximize
Drag window left/right: Dock the window to fill half of the screen.
Shake window back/forth: Minimize everything but the current window.
Double-Click Top Window Border (edge): Maximize window vertically.
Win+number (1-9): Starts the application pinned to the taskbar in that position, or switches to that program.
Shift+Win+number (1-9): Starts a new instance of the application pinned to the taskbar in that position.
Ctrl+Win+number (1-9): Cycles through open windows for the application pinned to the taskbar in that position.
Alt+Win+number (1-9): Opens the Jump List for the application pinned to the taskbar.
Win+T: Focus and scroll through items on the taskbar.
Win+B: Focuses the System Tray icons
In addition, you can interact with the taskbar using your mouse and a modifier key:
Shift+Click on a taskbar button: Open a program or quickly open another instance of a program.
Ctrl+Shift+Click on a taskbar button: Open a program as an administrator.
Shift+Right-click on a taskbar button: Show the window menu for the program (like XP does).
Shift+Right-click on a grouped taskbar button: Show the window menu for the group.
Ctrl+Click on a grouped taskbar button: Cycle through the windows of the group.
Here's a few more interesting hotkeys for you:
Ctrl+Shift+N: Creates a new folder in Windows Explorer.
Alt+Up: Goes up a folder level in Windows Explorer.
Alt+P: Toggles the preview pane in Windows Explorer.
Shift+Right-Click on a file: Adds Copy as Path, which copies the path of a file to the clipboard.
Shift+Right-Click on a file: Adds extra hidden items to the Send To menu.
Shift+Right-Click on a folder: Adds Command Prompt Here, which lets you easily open a command prompt in that folder.
Win+P: Adjust presentation settings for your display.
Win+(+/-): Zoom in/out.
Win+G: Cycle between the Windows Gadgets on your screen.
Win+L: Lock your workstation
Win+D: Display the desktop
Win+Spacebar: Preview desktop
Win+M: Minimize all windows
Win+Shift+M: Maximize all windows
Win+E: Open Computer
Win+R: Run dialog
Win+Home: Minimize all but active window
This list is in no way definitive, so if you discover a new shortcut, please do leave a comment...
Windows 7 resources
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